منابع مشابه
Sulfoxide-mediated Umpolung of alkali halide salts.
A new protocol for the direct two-electron oxidative Umpolung of alkali halide salts is reported. This procedure, relying on the use of a commercially available sulfoxide as the oxidant, allows the electrophilic halogenation of carbonyl compounds as well as halolactonisation reactions to proceed from the corresponding sodium salts, at room temperature and under mild conditions.
متن کاملRemoval of Heavy Metal and Halide Contamination from Macronutrient Salts.
In micronutrient deficiency experiments with plants the salts used to supply macronutrients must obviously be free of significant contamination. Hewitt (4), in reviewing the testing and purification of nutrient reagents, clearly pointed out that there is no guarantee that even the purest salts commercially available are sufficiently free of the known micronutrients, and that routine use of an a...
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The nuclear magnetic resonance ~NMR! spectra of the I53/2 monovalent ions Na, Cl, K, and Br for NaCl and KBr dissolved into filamentous bacteriophage Pf1 solutions display line splittings and shifts consistent with an interaction between the nuclear spin and the electric field gradient produced by the Pf1 particles. The average electric field gradient and thus the spectral splitting for ions in...
متن کاملInteraction of the model alkyltrimethylammonium ions with alkali halide salts: an explicit water molecular dynamics study¤
We present an explicit water molecular dynamics simulation of dilute solutions of model alkyltrimethylammonium surfactant ions (number of methylene groups in the tail is 3, 5, 8, 10, and 12) in mixture with NaF, NaCl, NaBr, and NaI salts, respectively. The SPC/E model is used to describe water molecules. Results of the simulation at 298 K are presented in the form of radial distribution functio...
متن کاملAsymmetric hydrogenation of quinazolinium salts catalysed by halide-bridged dinuclear iridium complexes bearing chiral diphosphine ligands.
Asymmetric hydrogenation of quinazolinium salts was catalysed by halogen-bridged dinuclear iridium complexes bearing chiral diphosphine ligands, yielding tetrahydroquinazoline and 3,4-dihydroquinazoline with high enantioselectivity. A derivative of chiral dihydroquinazoline was used as a chiral NHC ligand.
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ژورنال
عنوان ژورنال: Acta Physica Polonica A
سال: 2008
ISSN: 0587-4246,1898-794X
DOI: 10.12693/aphyspola.113.1659